Effect of organic dopants on electrodeposition and characteristics of polyaniline under the varying influence of H2SO4 and HClO4 electrolyte media

Electrodeposition of conducting polyaniline (Pani) was made under potentiostatic condition at pH 1.0 in different electrolyte media (H₂SO₄ and HClO₄) in the absence and presence of two organic dopants, disodium salts of naphthalene-1,5-disulphonic acid (NSA) and of catechol-3,5-disulphonic acid (CSA). The rate and yield of Pani deposition were dependent on the acid medium and the dopant employed. NSA in H₂SO₄ caused an increase in rate and yield but CSA decrease when compared to the rate and yield of H₂SO₄ alone. In HClO₄ medium, both the dopants showed a decrease. With regard to DC electrical conductivity, both the dopants exhibited an enhancement in H₂SO₄ medium but NSA a decline in HClO₄. Characterisation of the electrosynthesised polymer samples by various instrumental techniques (cyclic voltammetric: CV, FTIR, UV-Visible: UV-Vis, EPR, XRD, TGA and DTG methods) revealed that between the two acid media, H₂SO₄ was the better one. Further, it enlightened the role of two organic dopants in relation to the acid media. The advantageous role of NSA in H₂SO₄ had origin on its molecular characteristics such as non-polarity, larger π-electron cloud etc., while CSA could not perform such a role because of its easily oxidisable hydroxyl groups. In HClO₄, however, both the dopants could play only an unfavourable role owing to its greater polarity and oxidizing power than H₂SO₄.     

聚氨酯-聚丙烯酸酯共聚乳液的成膜和性能

通过XPS和接触角测试研究了聚氨酯-聚丙烯酸酯共聚乳液在不同基材上的成膜情况，并对共聚胶膜的耐水性和附着力进行了考察．由于该共聚乳液同时存在着亲水组分和疏水组分，所以它在不同的基材上成膜可导致其膜表面的组成成分不同，因而导致其耐水性和附着力也随基材而异。结果表明，亲水性的聚氨酯组分均富集于胶膜内部，但胶膜底层聚氨酯组分的含量却随基材的不同而不同。在憎水且表面张力较高的基材上，共聚胶膜的耐水性良好；共聚胶膜的附着力在表面张力较高的基材上也良好。     

双自由度后坐保险机构的计算机动态仿真

在Workin Model 3D软件上对引信的双自由度后坐保险机构进行了有关计算机仿真计算，并结合具体实例进行了优化设计。     

油藏数值模拟在油田开发调整中的应用——八面河油田面4区面3块开发调整方案研究

针对油藏现状,在油藏描述的基础上,进行网格划分,建立地质模型;根据生产历史资料建立动态模型;通过对油藏模型参数的分析,建立油藏数值模拟模型;应用数值模拟软件对面3块进行了三维三相油藏数值模拟研究。根据拟合成果提交了含水饱和度分布图、单位面积剩余储量分布图和各砂体储量状况表,分析了剩余油分布规律和油藏开发潜力,对面3块进行了调整方案设计和调整后的效果分析。     

基于四阶累积量的到达频率差估计算法

研究了基于四阶累积量的到达频率差估计算法，并给出了该算法的离散实现方法。该算法利用高阶累积量的特性，在相关的噪声环境下，对到达频率差作出了精确估计。仿真结果验证了该算法的有效性。     

高校电视台节目漫谈

结合高校校园电视台的职能和特点 ,深刻剖析了高校电视台几种类型节目的特点以及对高校校园文化的作用。     

基于虚拟仪器技术的火车闸片摩擦系数测试系统

虚拟仪器是当今仪器仪表发展的趋势，根据硬件结构、总线结构、开发平台的不同，虚拟仪嚣系统有一套典型开发步骤和系统构建方式。本文介绍了一个利用基于虚拟仪器技术的火车闸片摩擦系数测试系统的设计，给出了系统的硬件结构和软件设计的思路。     

建筑制图标准中图形符号适宜性、区分性的研究

应用线段长短、间距大小视觉反应的量化规律，提出设计图形符号大小的原则——既更使其大小满足“长”“短”“大”“小”的心理要求，又要互相之间在大小上有区分性。根据图形组织的相似、接近、连续三原则提出设计图形符号形状的原则——图形符号之间尽量减少相似、接近、连续，以保证较好的区分性。通过分析发现，现行建筑制图标准中的图形符号绝大部分在大小和形状具有适宜性、区分性。     

腐蚀环境中海工混凝土抗氯离子侵蚀性

模拟我国南方沿海浪溅区和水位变动区的海工钢筋混凝土结构物的腐蚀环境，对掺入粉煤灰和矿渣的混凝土抗氯离子侵蚀性进行了试验。结果表明，在水灰比相同的条件下，加掺和料的混凝土抗氯离子侵蚀性高于普通混凝土。     

Fodor and Pylyshyn on connectionism

Fodor and Pylyshyn (1988) have argued that the cognitive architecture is not Connectionist. Their argument takes the following form: (1) the cognitive architecture is Classical; (2) Classicalism and Connectionism are incompatible; (3) therefore the cognitive architecture is not Connectionist. In this essay I argue that Fodor and Pylyshyn's defenses of (1) and (2) are inadequate. Their argument for (1), based on their claim that Classicalism best explains the systematicity of cognitive capacities, is an invalid instance of inference to the best explanation. And their argument for (2) turns out to be question-begging. The upshot is that, while Fodor and Pylyshyn have presented Connectionists with the important empirical challenge of explaining systematicity, they have failed to provide sufficient reason for inferring that the cognitive architecture is Classical and not Connectionist.